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- W2337331723 abstract "We propose a nanostructured Mn-doped V2O5 lithium-ion battery cathode material that facilitates cathodic charge transport. The synthesis strategy uses a layered compound, vanadium(III) jarosite, as the precursor, in which the Mn2+ ions are doped uniformly between the vanadium oxide crystal layers. Through a two-step transformation, the vanadium jarosite was converted into Mn2+-doped V2O5. The resulting aliovalent doping of the larger Mn cations in the modified V2O5 structure increases the cell volume, which facilitates diffusion of Li+ ions, and introduces oxygen vacancies that improve the electronic conductivity. Comparison of the electrochemical performance in Li-ion batteries of undoped and the Mn2+-doped V2O5 hierarchical structure made from layered vanadium jarosite confirms that the Mn-doping improves ion transport to give a high cathodic columbic capacity (253 mAhg–1 at 1C, 86% of the theoretical value, 294 mAhg–1) and excellent cycling stability." @default.
- W2337331723 created "2016-06-24" @default.
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- W2337331723 date "2015-10-22" @default.
- W2337331723 modified "2023-09-28" @default.
- W2337331723 title "Nanostructured Mn-Doped V<sub>2</sub>O<sub>5</sub> Cathode Material Fabricated from Layered Vanadium Jarosite" @default.
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- W2337331723 doi "https://doi.org/10.1021/acs.chemmater.5b02840" @default.
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