Matches in SemOpenAlex for { <https://semopenalex.org/work/W2337339944> ?p ?o ?g. }
Showing items 1 to 81 of
81
with 100 items per page.
- W2337339944 abstract "The rich photophysics, photochemistry and electrochemistry of Ru II complexes have attracted intense research interest in widely disparate fields. A large portion of the studied and applied complexes are derived from the archetypical [Ru(bpy) 3 ] 2+ (bpy is 2,2’-bipyridine), which absorbs in the visible region, displays a long lived (~1 μs), emissive metal-to-ligand charge transfer state, and shows reversible electrochemistry in both the ground and excited state. Adding substituents to the bpy ligand is a conventional way of fine-tuning the physical properties. Incorporating larger motifs, altering the coordination sphere geometry or coordinating ligands via other heteroatoms than nitrogen can result in substantially different physical properties. This latter approach is the subject of this thesis, and in it I have presented the results from studies on structure complexes incorporating what I chose to call unconventional ligands. This thesis is focused on the structure-function relationships in three series of Ru II complexes: 1) With strained bpy-ligands, connected in the 3,3’-positions, with electron rich dithiol-motifs that display high light harvesting capabilities. Additionally, they promote hole-transfer when used for sensitizing a semiconductor substrate, with long-lived charge separated states. 2) Pyridine-thioether complexes that display excited state properties on par with [Ru(bpy) 3 ] 2+ and pyridine-sulfoxide complexes that display two-color reversible photo-isomerization in solution and immobilized on a semiconductor substrate. 3) Quinoline-pyrazole ligands that when coordinated form near perfect octahedral complexes; two of which display different selectivity toward photo-chlorination with respect to Cl - -source, and one that displays room temperature dynamic diastereomerization in the ground state while at the same time being extremely photo-stable." @default.
- W2337339944 created "2016-06-24" @default.
- W2337339944 creator A5065220500 @default.
- W2337339944 date "2016-01-01" @default.
- W2337339944 modified "2023-09-27" @default.
- W2337339944 title "Structure-Function Relationships in RuII Complexes with Unconventional Ligands: Photophysical and Photochemical Studies" @default.
- W2337339944 hasPublicationYear "2016" @default.
- W2337339944 type Work @default.
- W2337339944 sameAs 2337339944 @default.
- W2337339944 citedByCount "0" @default.
- W2337339944 crossrefType "dissertation" @default.
- W2337339944 hasAuthorship W2337339944A5065220500 @default.
- W2337339944 hasConcept C115624301 @default.
- W2337339944 hasConcept C116569031 @default.
- W2337339944 hasConcept C121332964 @default.
- W2337339944 hasConcept C123669783 @default.
- W2337339944 hasConcept C155647269 @default.
- W2337339944 hasConcept C161790260 @default.
- W2337339944 hasConcept C170493617 @default.
- W2337339944 hasConcept C178790620 @default.
- W2337339944 hasConcept C181500209 @default.
- W2337339944 hasConcept C185544564 @default.
- W2337339944 hasConcept C185592680 @default.
- W2337339944 hasConcept C20950531 @default.
- W2337339944 hasConcept C2779336533 @default.
- W2337339944 hasConcept C2779444094 @default.
- W2337339944 hasConcept C2779485729 @default.
- W2337339944 hasConcept C2780378348 @default.
- W2337339944 hasConcept C55493867 @default.
- W2337339944 hasConcept C555196967 @default.
- W2337339944 hasConcept C71240020 @default.
- W2337339944 hasConcept C75473681 @default.
- W2337339944 hasConcept C8010536 @default.
- W2337339944 hasConceptScore W2337339944C115624301 @default.
- W2337339944 hasConceptScore W2337339944C116569031 @default.
- W2337339944 hasConceptScore W2337339944C121332964 @default.
- W2337339944 hasConceptScore W2337339944C123669783 @default.
- W2337339944 hasConceptScore W2337339944C155647269 @default.
- W2337339944 hasConceptScore W2337339944C161790260 @default.
- W2337339944 hasConceptScore W2337339944C170493617 @default.
- W2337339944 hasConceptScore W2337339944C178790620 @default.
- W2337339944 hasConceptScore W2337339944C181500209 @default.
- W2337339944 hasConceptScore W2337339944C185544564 @default.
- W2337339944 hasConceptScore W2337339944C185592680 @default.
- W2337339944 hasConceptScore W2337339944C20950531 @default.
- W2337339944 hasConceptScore W2337339944C2779336533 @default.
- W2337339944 hasConceptScore W2337339944C2779444094 @default.
- W2337339944 hasConceptScore W2337339944C2779485729 @default.
- W2337339944 hasConceptScore W2337339944C2780378348 @default.
- W2337339944 hasConceptScore W2337339944C55493867 @default.
- W2337339944 hasConceptScore W2337339944C555196967 @default.
- W2337339944 hasConceptScore W2337339944C71240020 @default.
- W2337339944 hasConceptScore W2337339944C75473681 @default.
- W2337339944 hasConceptScore W2337339944C8010536 @default.
- W2337339944 hasLocation W23373399441 @default.
- W2337339944 hasOpenAccess W2337339944 @default.
- W2337339944 hasPrimaryLocation W23373399441 @default.
- W2337339944 hasRelatedWork W135787191 @default.
- W2337339944 hasRelatedWork W1630639489 @default.
- W2337339944 hasRelatedWork W1973450498 @default.
- W2337339944 hasRelatedWork W2007973185 @default.
- W2337339944 hasRelatedWork W2009542925 @default.
- W2337339944 hasRelatedWork W2017448072 @default.
- W2337339944 hasRelatedWork W2058035668 @default.
- W2337339944 hasRelatedWork W2069663629 @default.
- W2337339944 hasRelatedWork W2071753261 @default.
- W2337339944 hasRelatedWork W2078508896 @default.
- W2337339944 hasRelatedWork W2089679119 @default.
- W2337339944 hasRelatedWork W2170443874 @default.
- W2337339944 hasRelatedWork W2279739762 @default.
- W2337339944 hasRelatedWork W2313702392 @default.
- W2337339944 hasRelatedWork W2325333776 @default.
- W2337339944 hasRelatedWork W2333654929 @default.
- W2337339944 hasRelatedWork W2891257953 @default.
- W2337339944 hasRelatedWork W3214027256 @default.
- W2337339944 hasRelatedWork W294396990 @default.
- W2337339944 hasRelatedWork W2962544265 @default.
- W2337339944 isParatext "false" @default.
- W2337339944 isRetracted "false" @default.
- W2337339944 magId "2337339944" @default.
- W2337339944 workType "dissertation" @default.