Matches in SemOpenAlex for { <https://semopenalex.org/work/W2337812312> ?p ?o ?g. }
- W2337812312 endingPage "207" @default.
- W2337812312 startingPage "163" @default.
- W2337812312 abstract "Oxygen evolution by photosynthetic water oxidation has shaped life on planet Earth. This unique biological reaction may provide important clues for developing artificial devices (‘artificial leaves’) for splitting water into O2 and H2 by visible light. In this chapter, we summarize the latest structural and mechanistic information on photosystem II, its water-oxidizing complex (WOC), and O2 formation from water at its Mn4CaO5 cluster. Structural information on the WOC derived by X-ray crystallography, X-ray spectroscopy, EPR/ENDOR, and theoretical approaches are compared and discussed in detail. After a description of the basic mechanism of water-oxidation (Kok model), our knowledge about the storage of oxidizing equivalents, substrate water-binding, the release of the products O2 and H+, and the energetics of water-oxidation is described. The near electroneutrality of the water-splitting process via coupling of electron and proton transfer steps and the stabilization of the initial light-driven charge separation by spatial separation and heat dissipation are emphasized as important design principles for coupling fast photochemistry with comparatively slow chemical reactions. The chapter concludes with a discussion of recent DFT-based mechanistic proposals for photosynthetic water oxidation, and with an attempt to identify lessons for the design of artificial systems." @default.
- W2337812312 created "2016-06-24" @default.
- W2337812312 creator A5005651755 @default.
- W2337812312 creator A5045637353 @default.
- W2337812312 creator A5087040660 @default.
- W2337812312 date "2011-12-19" @default.
- W2337812312 modified "2023-09-24" @default.
- W2337812312 title "Photosynthetic O2 Evolution" @default.
- W2337812312 cites W1087938070 @default.
- W2337812312 cites W136642043 @default.
- W2337812312 cites W1508382797 @default.
- W2337812312 cites W1545133982 @default.
- W2337812312 cites W1570345623 @default.
- W2337812312 cites W1961714136 @default.
- W2337812312 cites W1963482869 @default.
- W2337812312 cites W1963597613 @default.
- W2337812312 cites W1964274154 @default.
- W2337812312 cites W1964738515 @default.
- W2337812312 cites W1964927034 @default.
- W2337812312 cites W1965022884 @default.
- W2337812312 cites W1965859647 @default.
- W2337812312 cites W1966917335 @default.
- W2337812312 cites W1967116724 @default.
- W2337812312 cites W1967250117 @default.
- W2337812312 cites W1967695001 @default.
- W2337812312 cites W1968489731 @default.
- W2337812312 cites W1968551953 @default.
- W2337812312 cites W1969784611 @default.
- W2337812312 cites W1970481153 @default.
- W2337812312 cites W1971727731 @default.
- W2337812312 cites W1973132235 @default.
- W2337812312 cites W1973628353 @default.
- W2337812312 cites W1973721002 @default.
- W2337812312 cites W1973771294 @default.
- W2337812312 cites W1974058427 @default.
- W2337812312 cites W1975418946 @default.
- W2337812312 cites W1975878413 @default.
- W2337812312 cites W1975954782 @default.
- W2337812312 cites W1976036023 @default.
- W2337812312 cites W1976389530 @default.
- W2337812312 cites W1976477575 @default.
- W2337812312 cites W1976818531 @default.
- W2337812312 cites W1977092091 @default.
- W2337812312 cites W1977184032 @default.
- W2337812312 cites W1977535375 @default.
- W2337812312 cites W1977658668 @default.
- W2337812312 cites W1978136157 @default.
- W2337812312 cites W1981768663 @default.
- W2337812312 cites W1981892500 @default.
- W2337812312 cites W1982351418 @default.
- W2337812312 cites W1983344496 @default.
- W2337812312 cites W1983862582 @default.
- W2337812312 cites W1984527732 @default.
- W2337812312 cites W1987815088 @default.
- W2337812312 cites W1987878085 @default.
- W2337812312 cites W1987946602 @default.
- W2337812312 cites W1989193332 @default.
- W2337812312 cites W1989200553 @default.
- W2337812312 cites W1990326465 @default.
- W2337812312 cites W1994268852 @default.
- W2337812312 cites W1995414833 @default.
- W2337812312 cites W1995994720 @default.
- W2337812312 cites W1996077709 @default.
- W2337812312 cites W1996917852 @default.
- W2337812312 cites W1999632228 @default.
- W2337812312 cites W2000037965 @default.
- W2337812312 cites W2000046331 @default.
- W2337812312 cites W2001336392 @default.
- W2337812312 cites W2001894715 @default.
- W2337812312 cites W2003872574 @default.
- W2337812312 cites W2009029329 @default.
- W2337812312 cites W2009107609 @default.
- W2337812312 cites W2010213346 @default.
- W2337812312 cites W2010278274 @default.
- W2337812312 cites W2012490901 @default.
- W2337812312 cites W2012926691 @default.
- W2337812312 cites W2013164036 @default.
- W2337812312 cites W2013526703 @default.
- W2337812312 cites W2016035644 @default.
- W2337812312 cites W2016156461 @default.
- W2337812312 cites W2016629142 @default.
- W2337812312 cites W2016712088 @default.
- W2337812312 cites W2016807165 @default.
- W2337812312 cites W2017781434 @default.
- W2337812312 cites W2018211671 @default.
- W2337812312 cites W2019299030 @default.
- W2337812312 cites W2019962788 @default.
- W2337812312 cites W2020135094 @default.
- W2337812312 cites W2020164840 @default.
- W2337812312 cites W2022085399 @default.
- W2337812312 cites W2022654083 @default.
- W2337812312 cites W2023079039 @default.
- W2337812312 cites W2023116072 @default.
- W2337812312 cites W2024162666 @default.
- W2337812312 cites W2024286455 @default.
- W2337812312 cites W2024542880 @default.
- W2337812312 cites W2024621625 @default.
- W2337812312 cites W2026454297 @default.