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• W2338202342 endingPage "17241" @default.
• W2338202342 startingPage "17238" @default.
• W2338202342 abstract "Organic N-containing compounds, including amines, are essential components of many biologically and pharmaceutically important molecules. One strategy for introducing nitrogen into substrates with multiple reactive bonds is to insert a monovalent N fragment (nitrene or nitrenoid) into a C-H bond or add it directly to a C═C bond. However, it has been challenging to develop well-defined catalysts capable of promoting predictable and chemoselective aminations solely through reagent control. Herein, we report remarkable chemoselective aminations that employ a single metal (Ag) and a single ligand (phenanthroline) to promote either aziridination or C-H insertion by manipulating the coordination geometry of the active catalysts." @default.
• W2338202342 created "2016-06-24" @default.
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• W2338202342 date "2013-11-11" @default.
• W2338202342 modified "2023-09-25" @default.
• W2338202342 title "Tunable, Chemoselective Amination <i>via</i> Silver Catalysis" @default.
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• W2338202342 doi "https://doi.org/10.1021/ja406654y" @default.
• W2338202342 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4492479" @default.
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• W2338202342 hasPublicationYear "2013" @default.
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