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- W2339142012 abstract "We map buried hydrogen-bonding networks within self-assembled monolayers of 3-mercapto-N-nonylpropionamide on Au{111}. The contributing interactions include the buried S–Au bonds at the substrate surface and the buried plane of linear networks of hydrogen bonds. Both are simultaneously mapped with submolecular resolution, in addition to the exposed interface, to determine the orientations of molecular segments and directional bonding. Two-dimensional mode-decomposition techniques are used to elucidate the directionality of these networks. We find that amide-based hydrogen bonds cross molecular domain boundaries and areas of local disorder." @default.
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- W2339142012 date "2016-04-25" @default.
- W2339142012 modified "2023-10-18" @default.
- W2339142012 title "Mapping Buried Hydrogen-Bonding Networks" @default.
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- W2339142012 doi "https://doi.org/10.1021/acsnano.6b01717" @default.
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