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- W2339244358 abstract "The electroreduction of corannulene (C20H10) has been investigated in a room temperature ionic liquid (RTIL) for the first time. In the RTIL 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide ([Bmpyrr][NTf2]) the resultant voltammetry shows a peak-to-peak separation of 100 mV, and this separation does not vary with scan rate (as predicted by a simple E mechanism). We propose a square scheme that is capable of accurately describing this behavior. Specifically, the use of a square scheme takes into account the effect of ion pairing between the ionic liquid cation and the corannulene anion on the overall reaction mechanism. Importantly, investigation in acetonitrile with a range of conventional electrolytes does not display the trends observed in the RTIL. This result likely provides a general insight into all RTILs as a class of electrolyte, because of the high concentration of ions and the proclivity of RTILs to ion-pair." @default.
- W2339244358 created "2016-06-24" @default.
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- W2339244358 date "2016-04-13" @default.
- W2339244358 modified "2023-10-06" @default.
- W2339244358 title "The Corannulene Reduction Mechanism in Ionic Liquids is Controlled by Ion Pairing" @default.
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- W2339244358 doi "https://doi.org/10.1021/acs.jpcc.6b02551" @default.
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