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• W2339805383 abstract "The effects of isovalent doping on orbital ordering in the perovskite ${mathrm{Y}}_{1ensuremath{-}x}{mathrm{La}}_{x}{mathrm{VO}}_{3}$ were investigated using neutron diffraction and the pair distribution function analysis. ${mathrm{YVO}}_{3}$ is a prototype for orbital ordering, exhibiting two consecutive transitions to G-type and C-type ordering with decreasing temperature. Evidence for local orbital ordering above the transition temperature of ${T}_{OO}ensuremath{sim}200$ K is presented, obtained from the temperature dependence of the oxygen-oxygen octahedral correlations. This suggests that locally, G-type orbital ordering is present above the ${T}_{OO}$ temperature but it is short range. With doping, it is expected that orbital ordering disappears altogether. By 30% of doping, as in ${mathrm{Y}}_{0.7}{mathrm{La}}_{0.3}{mathrm{VO}}_{3}$, even though no orbital ordering is expected, we find that locally, C-type orbital correlations are most likely present below the magnetic transition temperature ${T}_{N}$, allowing for a direct paramagnetic to orbitally ordered/antiferromagnetic transition in this composition." @default.
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• W2339805383 date "2014-12-31" @default.
• W2339805383 modified "2023-09-27" @default.
• W2339805383 title "<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mrow><mml:msub><mml:mi mathvariant=normal>Y</mml:mi><mml:mrow><mml:mn>1</mml:mn><mml:mo>−</mml:mo><mml:mi>x</mml:mi></mml:mrow></mml:msub><mml:msub><mml:mi>La</mml:mi><mml:mi>x</mml:mi></mml:msub><mml:msub><mml:mi>VO</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>: Effects of doping on orbital ordering" @default.
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• W2339805383 doi "https://doi.org/10.1103/physrevb.90.214111" @default.
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