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- W2339911373 abstract "Polyhydride metal complexes are being developed for application to hydrogen storage. Complexes have been found which catalyze the reversible hydrogenation of unsaturated hydrocarbons. This catalytic reaction could be the basis for a low temperature, hydrogen storage system with a available hydrogen density greater than 7 weight percent. The P-C-P pincer complexes, RhH{sub 2}(C{sub 6}H{sub 3}-2,6-(CH{sub 2}PBu{sup t}{sub 2}){sub 2}) and IrH{sub 2}(C{sub 6}H{sub 3}-2,6-(CH{sub 2}PBu{sup t}{sub 2}){sub 2}) have unprecedented, long term stability at elevated temperatures. The novel iridium complex catalyzes the transfer dehydrogenation of cycloctane to cyclooctene at the rate of 716 turnovers/h which is 2 orders of magnitude greater than that found for previously reported catalytic systems which do not require the sacrificial hydrogenation of a large excess of hydrogen acceptor." @default.
- W2339911373 created "2016-06-24" @default.
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- W2339911373 date "1996-10-01" @default.
- W2339911373 modified "2023-09-23" @default.
- W2339911373 title "Hydrogen storage via polyhydride complexes" @default.
- W2339911373 hasPublicationYear "1996" @default.
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