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- W2340118563 abstract "ABSTRACTThe unit cell dimensions of vanadium, NaCl and Au have been collected to 11. 5 GPa and 1000 K by powder X-ray diffraction and are used to constrain a practical high-temperature EoS for bcc vanadium. The resulting third-order Birch–Murnaghan EoS is described with parameters KT0,300 = 150.4 ± 6.2 GPa, KT′ = 5.5 ± 1.0, α0 = 4.8(6)·10−5, α1 = −2.4(9)·10−8 and δKTδT = −0.0446(7) GPa/K. The parameter α.K0,300 is 616·10−5 K−1 GPa and reduces to zero at an estimated 60 GPa at RT. This EoS description is entirely consistent with the majority of X-ray, ultrasonic, shock wave and calculated data-sets in this p, T range. These measurements facilitate the estimation of in situ temperatures under high pressures when vanadium is used inside sample assemblies and are useful, when used with h-BN, to estimate p, T over the full range of h-BN stability." @default.
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- W2340118563 date "2016-01-02" @default.
- W2340118563 modified "2023-09-24" @default.
- W2340118563 title "High-temperature equation of state of vanadium" @default.
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- W2340118563 doi "https://doi.org/10.1080/08957959.2015.1123256" @default.
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