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- W2340179244 abstract "We disclosed therein a new reaction of reductive isomerization of methylenecyclopropanes (MCPs) to vinylcyclopropanes (VCPs). On treatment with sodium metal in liquid ammonia, MCPs bearing a C–O bond at allylic position undergo both a reductive cleavage of the C–O bond and an isomerization of the C–C double bond giving rise to VCPs. The scope of the reductive isomerization was investigated and showed a broad applicability since various functional groups are tolerated. MCP substrates were straightforwardly prepared by a palladium-promoted [2 + 1] cycloaddition between norbornene derivatives with alkynes." @default.
- W2340179244 created "2016-06-24" @default.
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- W2340179244 date "2015-08-24" @default.
- W2340179244 modified "2023-10-05" @default.
- W2340179244 title "Preparation of Vinylcyclopropanes by Sodium Mediated Reductive Isomerization of Methylenecyclopropanes" @default.
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- W2340179244 doi "https://doi.org/10.1021/acs.joc.5b01205" @default.
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