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• W2340287515 abstract "A series of half‐sandwich ruthenium(II) arene complexes [( η 6 ‐ p ‐cymene)Ru II (R‐BzTSC)Cl]Cl 1 , 2 , 3 (BzTSC = benzaldehyde thiosemicarbazone and R = H, CH 3 and C 6 H 5 ) have been synthesized and characterized by IR, 1 H NMR, UV‐visible, electrospray ionization mass spectrometry and elemental analysis. The single‐crystal structures of 1 and 3 have been determined. The molecular orbitals and electronic absorption spectra of the compounds have been calculated using the DFT and TDDFT methods. The in vitro antiproliferative activities of these complexes have been evaluated against four human cancer cell lines (CNE, H292, SKBR3 and Hey1‐B), and 3 is proved to be the most efficient inhibitor, with IC 50 values of 20, 31, 10 and 34 μ m , respectively. Copyright © 2013 John Wiley & Sons, Ltd." @default.
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• W2340287515 date "2013-04-11" @default.
• W2340287515 modified "2023-10-14" @default.
• W2340287515 title "Synthesis, crystal and electronic structure, anticancer activity of ruthenium(II) arene complexes with thiosemicarbazones" @default.
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• W2340287515 doi "https://doi.org/10.1002/aoc.2977" @default.
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