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- W2340386084 abstract "Cobalt-catalyzed carboxyzincation reactions employing carbon dioxide and zinc metal powder are developed. By using alkynes as substrates, regio- and stereodefined (Z)-β-zincated acrylates are provided. The corresponding alkenylzinc moiety can be converted to various substituents, affording multisubstituted acrylic acids. Furthermore, by adding electron-deficient alkene to the reaction system, the four-component coupling reactions of alkyne, alkene, CO2, and the Zn atom proceed via carboxyzincation." @default.
- W2340386084 created "2016-06-24" @default.
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- W2340386084 date "2016-04-22" @default.
- W2340386084 modified "2023-10-17" @default.
- W2340386084 title "Carboxyzincation Employing Carbon Dioxide and Zinc Powder: Cobalt-Catalyzed Multicomponent Coupling Reactions with Alkynes" @default.
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- W2340386084 doi "https://doi.org/10.1021/jacs.6b02961" @default.
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