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- W2340597584 abstract "The parent phosphinidene-carbene adduct NHC=PH is a versatile synthon in main group chemistry and can act as an electronically flexible ligand for transition metals. Previously, it could only be synthesized with sterically demanding N-aryl substituents. This paper describes simple methods for the synthesis of NHC=PH adducts with varying steric demand from elemental phosphorus or easily accessible phosphorus sources. Furthermore, the reactivity of NHCs towards PH3 was investigated. It was shown how a NHC inserts into the P-H bond of PH3, which opens up a route to NHC=PH adducts from an imidazolium salt and PH3. The adducts were used in the simple syntheses of bis(phosphinidene) mercury(<small>II</small>) and group 6 pentacarbonyl parent phosphinidene complexes. Their electronic and structural properties were investigated to elucidate the influence of the NHC on the phosphinidene and identify possible applications." @default.
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- W2340597584 date "2016-04-27" @default.
- W2340597584 modified "2023-10-16" @default.
- W2340597584 title "PH3 as a Phosphorus Source for Phosphinidene–Carbene Adducts and Phosphinidene–Transition Metal Complexes" @default.
- W2340597584 doi "https://doi.org/10.2533/chimia.2016.279" @default.
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