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- W2340653485 abstract "Abstract The gold‐catalyzed enantioselective hydroazidation and hydroamination reactions of allenes are presented herein. ADC gold(I) catalysts derived from BINAM were critical for achieving high levels of enantioselectivity in both transformations. The sense of enantioinduction is reversed for the two different nucleophiles, allowing access to both enantiomers of the corresponding allylic amines using the same catalyst enantiomer." @default.
- W2340653485 created "2016-06-24" @default.
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- W2340653485 date "2016-04-20" @default.
- W2340653485 modified "2023-10-07" @default.
- W2340653485 title "Enantioselective, Stereodivergent Hydroazidation and Hydroamination of Allenes Catalyzed by Acyclic Diaminocarbene (ADC) Gold(I) Complexes" @default.
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- W2340653485 doi "https://doi.org/10.1002/anie.201601550" @default.
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