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• W2340659653 endingPage "6514" @default.
• W2340659653 startingPage "6511" @default.
• W2340659653 abstract "Excellent enantioselectivities (up to 97 % ee) and diastereoselectivities (up to >99:1 d.r.) have been achieved in the desymmetrization of cyclopentenes by catalytic hydroformylation. This novel methodology provides an efficient and concise synthetic route to chiral cyclopentane carboxaldehydes. The key intermediate, (1S,3S)-(3-hydroxymethyl)cyclopentanol, for the synthesis of carbocyclic-ddA was obtained in three steps." @default.
• W2340659653 created "2016-06-24" @default.
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• W2340659653 date "2016-04-18" @default.
• W2340659653 modified "2023-10-17" @default.
• W2340659653 title "Rhodium-Catalyzed Desymmetrization by Hydroformylation of Cyclopentenes: Synthesis of Chiral Carbocyclic Nucleosides" @default.
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• W2340659653 doi "https://doi.org/10.1002/anie.201601478" @default.
• W2340659653 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27086543" @default.
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