Matches in SemOpenAlex for { <https://semopenalex.org/work/W2340690032> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W2340690032 abstract "Carbenes have a long history of being classed as highly reactive species, whose isolation was deemed impossible. However, a paradigm shift occurred over two decades ago when the first stable carbene was reported. Since then, the field of stable carbene chemistry has flourished and applications in numerous fields of chemistry have been found. One unlikely application comes from their ability to act as stabilizing entities. Indeed, a wide variety of previously unattainable transition metal and main group species have been isolated via carbene stabilization. In this manuscript, carbenes will be utilized to isolate highly reactive species based on Group 13 and 15 elements. The first part of this manuscript will describe the design and synthesis of boron centered nucleophiles supported by carbenes. Then, it will be shown that the steric environment of the carbene plays a pivotal role in protecting a highly reactive fragment. The electronic properties of carbenes are also a crucial characteristic to consider and we demonstrate that with the appropriate carbene framework, a single element can be stabilized in several oxidation states. Finally, we will demonstrate that a phosphorus analogue of a carbene, which has eluded isolation so far, can be stabilized with the appropriate framework." @default.
- W2340690032 created "2016-06-24" @default.
- W2340690032 creator A5051834001 @default.
- W2340690032 date "2015-01-01" @default.
- W2340690032 modified "2023-09-27" @default.
- W2340690032 title "Stabilization of Highly Reactive Group 13 and 15 Species" @default.
- W2340690032 hasPublicationYear "2015" @default.
- W2340690032 type Work @default.
- W2340690032 sameAs 2340690032 @default.
- W2340690032 citedByCount "0" @default.
- W2340690032 crossrefType "journal-article" @default.
- W2340690032 hasAuthorship W2340690032A5051834001 @default.
- W2340690032 hasConcept C106773901 @default.
- W2340690032 hasConcept C138973236 @default.
- W2340690032 hasConcept C161790260 @default.
- W2340690032 hasConcept C178790620 @default.
- W2340690032 hasConcept C178907741 @default.
- W2340690032 hasConcept C185592680 @default.
- W2340690032 hasConcept C192937433 @default.
- W2340690032 hasConcept C201194858 @default.
- W2340690032 hasConcept C21951064 @default.
- W2340690032 hasConcept C2777164566 @default.
- W2340690032 hasConcept C2781311116 @default.
- W2340690032 hasConcept C54281723 @default.
- W2340690032 hasConcept C86914705 @default.
- W2340690032 hasConceptScore W2340690032C106773901 @default.
- W2340690032 hasConceptScore W2340690032C138973236 @default.
- W2340690032 hasConceptScore W2340690032C161790260 @default.
- W2340690032 hasConceptScore W2340690032C178790620 @default.
- W2340690032 hasConceptScore W2340690032C178907741 @default.
- W2340690032 hasConceptScore W2340690032C185592680 @default.
- W2340690032 hasConceptScore W2340690032C192937433 @default.
- W2340690032 hasConceptScore W2340690032C201194858 @default.
- W2340690032 hasConceptScore W2340690032C21951064 @default.
- W2340690032 hasConceptScore W2340690032C2777164566 @default.
- W2340690032 hasConceptScore W2340690032C2781311116 @default.
- W2340690032 hasConceptScore W2340690032C54281723 @default.
- W2340690032 hasConceptScore W2340690032C86914705 @default.
- W2340690032 hasLocation W23406900321 @default.
- W2340690032 hasOpenAccess W2340690032 @default.
- W2340690032 hasPrimaryLocation W23406900321 @default.
- W2340690032 hasRelatedWork W1505393295 @default.
- W2340690032 hasRelatedWork W1975592132 @default.
- W2340690032 hasRelatedWork W1981461678 @default.
- W2340690032 hasRelatedWork W2010676496 @default.
- W2340690032 hasRelatedWork W2015262040 @default.
- W2340690032 hasRelatedWork W2059112994 @default.
- W2340690032 hasRelatedWork W2104057453 @default.
- W2340690032 hasRelatedWork W2134085948 @default.
- W2340690032 hasRelatedWork W2135966828 @default.
- W2340690032 hasRelatedWork W2314303973 @default.
- W2340690032 hasRelatedWork W2461223532 @default.
- W2340690032 hasRelatedWork W2517974222 @default.
- W2340690032 hasRelatedWork W2767300230 @default.
- W2340690032 hasRelatedWork W2949924261 @default.
- W2340690032 hasRelatedWork W2950544192 @default.
- W2340690032 hasRelatedWork W2952990224 @default.
- W2340690032 hasRelatedWork W3086337602 @default.
- W2340690032 hasRelatedWork W3097762258 @default.
- W2340690032 hasRelatedWork W3138926056 @default.
- W2340690032 hasRelatedWork W4442095 @default.
- W2340690032 isParatext "false" @default.
- W2340690032 isRetracted "false" @default.
- W2340690032 magId "2340690032" @default.
- W2340690032 workType "article" @default.