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- W2340706861 abstract "Three Schiff base ligands containing two pyridine rings, S1, S2, and S3, show strong gelation abilities with AgNO3 in several pure or mixed solvents at room temperature. 1H NMR and Fourier transform infrared spectroscopy measurements not only demonstrated the coordination interaction between silver ion and nitrogen atom of the pyridine ring of the S2 ligand in S2-Ag metallogel, but also showed that hydrogen bonding contributes to the formation of the metallogels. In particular, S2-Ag metallogel shows a super smart and fully reversible thixotropic property, which has been rarely reported before in metallogels. X-ray diffraction (XRD) analysis revealed that S2-Ag metallogel in DMF takes a mixture of hexagonal and tetragonal packing modes. On the basis of the results of XRD and mass spectrometry analysis, a possible structure evolution process for the gel was proposed. And this model was further demonstrated by the results of polarizing microscopy and thermogravimetric analysis of S2-Ag metallogel." @default.
- W2340706861 created "2016-06-24" @default.
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- W2340706861 date "2015-10-16" @default.
- W2340706861 modified "2023-10-17" @default.
- W2340706861 title "Ag(I)-Coordinated Supramolecular Metallogels Based on Schiff Base Ligands: Structural Characterization and Reversible Thixotropic Property" @default.
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- W2340706861 doi "https://doi.org/10.1021/acs.cgd.5b00952" @default.
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