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- W2340760037 abstract "Although “soft ionisation” methods are highly recommended to be suitable for accurate molecular weight determination and the structure elucidation of peptides (1) and other polar organic compounds (2) there are many difficulties encountered in practice (3), resulting from the lack of sequence-specific ions. Sometimes such ions are present, sometimes not, why? As recently shown (4), derivatisation may enhance the tendency to produce fragment-specific ions. This is a strong indication that we should be able to direct the production of ions in a desired way if we would know more about the mechanism of fragment production. Peptides are of rather complicated composition, containing basic, acidic and neutral functions within one molecule. This makes investigations about the fragmentation mechanism difficult. We therefore started with the investigation of molecules with only one functional group." @default.
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- W2340760037 date "1986-01-01" @default.
- W2340760037 modified "2023-09-27" @default.
- W2340760037 title "Some Experiments on the Production of Ions in Soft Ionisation Mass Spectrometry" @default.
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- W2340760037 doi "https://doi.org/10.1007/978-3-642-82718-1_25" @default.
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