FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2340966669> ?p ?o ?g. }

• W2340966669 endingPage "10050" @default.
• W2340966669 startingPage "10041" @default.
• W2340966669 abstract "The pKa of the p-mercaptobenzoic acid (pMBA) ligands in the Au102(pMBA)44 nanocluster was measured by using acid–base and IR titration. The observed macroscopic pKa = 6.18 ± 0.05 is significantly more basic than that of free pMBA (pKa = 4.16), and the protonation behavior is anticooperative according to the Hill coefficient n = 0.64 ± 0.04. The cluster is truly water-soluble when more than 22 and insoluble when fewer than 7 ligands are in the deprotonated state. In order to obtain more insight into the anticooperative character, the cluster was modeled at pH ∼6.2 using constant pH molecular dynamics simulations. The pKa values of the individual pMBAs are in the range of 5.18–7.58, depending on the positions of the ligands, generating a nonuniform charge distribution on the cluster surface. The cluster interactions with inorganic and biological environment depend on the surface charge distribution, stressing the importance of understanding the protonation state of the cluster." @default.
• W2340966669 created "2016-06-24" @default.
• W2340966669 creator A5020046323 @default.
• W2340966669 creator A5027815151 @default.
• W2340966669 creator A5030041968 @default.
• W2340966669 creator A5049146628 @default.
• W2340966669 creator A5051858749 @default.
• W2340966669 creator A5070936021 @default.
• W2340966669 creator A5076428337 @default.
• W2340966669 date "2016-05-04" @default.
• W2340966669 modified "2023-09-24" @default.
• W2340966669 title "Acid–Base Properties and Surface Charge Distribution of the Water-Soluble Au₁₀₂(<i>p</i>MBA)₄₄ Nanocluster" @default.
• W2340966669 cites W1702208994 @default.
• W2340966669 cites W1904591906 @default.
• W2340966669 cites W1972550367 @default.
• W2340966669 cites W1976499671 @default.
• W2340966669 cites W1979013297 @default.
• W2340966669 cites W1979206321 @default.
• W2340966669 cites W1981021420 @default.
• W2340966669 cites W1983494079 @default.
• W2340966669 cites W1988661754 @default.
• W2340966669 cites W1992893536 @default.
• W2340966669 cites W1996313905 @default.
• W2340966669 cites W2005006118 @default.
• W2340966669 cites W2007789377 @default.
• W2340966669 cites W2014555232 @default.
• W2340966669 cites W2018079761 @default.
• W2340966669 cites W2018293384 @default.
• W2340966669 cites W2024292658 @default.
• W2340966669 cites W2027154929 @default.
• W2340966669 cites W2027909608 @default.
• W2340966669 cites W2035266068 @default.
• W2340966669 cites W2038280350 @default.
• W2340966669 cites W2046102151 @default.
• W2340966669 cites W2048322679 @default.
• W2340966669 cites W2065377374 @default.
• W2340966669 cites W2073534398 @default.
• W2340966669 cites W2074379564 @default.
• W2340966669 cites W2077228161 @default.
• W2340966669 cites W2079890449 @default.
• W2340966669 cites W2082960348 @default.
• W2340966669 cites W2088499999 @default.
• W2340966669 cites W2089495268 @default.
• W2340966669 cites W2093279818 @default.
• W2340966669 cites W2094449638 @default.
• W2340966669 cites W2094848101 @default.
• W2340966669 cites W2101863112 @default.
• W2340966669 cites W2103945336 @default.
• W2340966669 cites W2107519814 @default.
• W2340966669 cites W2109055414 @default.
• W2340966669 cites W2110479326 @default.
• W2340966669 cites W2114661560 @default.
• W2340966669 cites W2115803851 @default.
• W2340966669 cites W2123768693 @default.
• W2340966669 cites W2127639535 @default.
• W2340966669 cites W2128572087 @default.
• W2340966669 cites W2128871544 @default.
• W2340966669 cites W2132314137 @default.
• W2340966669 cites W2137399565 @default.
• W2340966669 cites W2140537016 @default.
• W2340966669 cites W2166478478 @default.
• W2340966669 cites W2167278129 @default.
• W2340966669 cites W2171268876 @default.
• W2340966669 cites W2252309414 @default.
• W2340966669 cites W2260308255 @default.
• W2340966669 cites W2286339724 @default.
• W2340966669 cites W2307833820 @default.
• W2340966669 cites W2312345857 @default.
• W2340966669 cites W2314715664 @default.
• W2340966669 cites W2319366294 @default.
• W2340966669 cites W2329291751 @default.
• W2340966669 cites W2329664077 @default.
• W2340966669 cites W2333359644 @default.
• W2340966669 cites W2333995949 @default.
• W2340966669 cites W2421711748 @default.
• W2340966669 cites W4241843748 @default.
• W2340966669 doi "https://doi.org/10.1021/acs.jpcc.6b00922" @default.
• W2340966669 hasPublicationYear "2016" @default.
• W2340966669 type Work @default.
• W2340966669 sameAs 2340966669 @default.
• W2340966669 citedByCount "44" @default.
• W2340966669 countsByYear W23409666692016 @default.
• W2340966669 countsByYear W23409666692017 @default.
• W2340966669 countsByYear W23409666692018 @default.
• W2340966669 countsByYear W23409666692019 @default.
• W2340966669 countsByYear W23409666692020 @default.
• W2340966669 countsByYear W23409666692021 @default.
• W2340966669 countsByYear W23409666692022 @default.
• W2340966669 countsByYear W23409666692023 @default.
• W2340966669 crossrefType "journal-article" @default.
• W2340966669 hasAuthorship W2340966669A5020046323 @default.
• W2340966669 hasAuthorship W2340966669A5027815151 @default.
• W2340966669 hasAuthorship W2340966669A5030041968 @default.
• W2340966669 hasAuthorship W2340966669A5049146628 @default.
• W2340966669 hasAuthorship W2340966669A5051858749 @default.
• W2340966669 hasAuthorship W2340966669A5070936021 @default.
• W2340966669 hasAuthorship W2340966669A5076428337 @default.
• W2340966669 hasConcept C113196181 @default.

• next