Matches in SemOpenAlex for { <https://semopenalex.org/work/W2341004048> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W2341004048 abstract "Ternary Cu/Zn/Cr oxide catalysts were prepared via hydrotalcite-like precursors and doped with Cs. The reference activity test (310{degrees}C, 7.6 MPa, Hz/CO = 0.45, GHSV = 5330 {ell}/kg{sub cat}/hr) was in full agreement with our previous results; 20.2% CO conversion, methanol yield of {approx}230 g/kg{sub cat}/hr, and productivity to higher alcohols of nearly 100 g/kg{sub cat}/hr. In order to enhance HAS and to better characterize the thermal behavior of the catalyst, the reaction temperature was increased to 340{degrees}C. As expected, methanol production decreased due to the relevant thermodynamic constraint, and increased formation of branched products due to kinetic promotion of the chain growth reactions was observed. The effect of H{sub 2}/CO feed ratio was studied in the range of 0.45-3.0, and it was observed that higher H{sub 2}/CO ratios could be used to advantage at higher temperatures, e.g. 0.75 was the optimal value with respect to isobutanol productivity at 340{degrees}C. The effect of contact time was also studied. Stable catalytic activity was observed for a period of 320 hr (150 hr at high temperature). No reduction of surface area and no significant sintering phenomena were observed after testing (particle size of metallic Cu {approx}60 {Angstrom})." @default.
- W2341004048 created "2016-06-24" @default.
- W2341004048 creator A5000185586 @default.
- W2341004048 creator A5029301165 @default.
- W2341004048 creator A5036887828 @default.
- W2341004048 creator A5063136693 @default.
- W2341004048 date "1995-12-01" @default.
- W2341004048 modified "2023-09-22" @default.
- W2341004048 title "Higher alcohol synthesis over Cs-doped Cu/Zn/Cr oxide catalysts: Effect of reaction temperature on the product distribution and catalyst stability" @default.
- W2341004048 hasPublicationYear "1995" @default.
- W2341004048 type Work @default.
- W2341004048 sameAs 2341004048 @default.
- W2341004048 citedByCount "0" @default.
- W2341004048 crossrefType "journal-article" @default.
- W2341004048 hasAuthorship W2341004048A5000185586 @default.
- W2341004048 hasAuthorship W2341004048A5029301165 @default.
- W2341004048 hasAuthorship W2341004048A5036887828 @default.
- W2341004048 hasAuthorship W2341004048A5063136693 @default.
- W2341004048 hasConcept C113196181 @default.
- W2341004048 hasConcept C134121241 @default.
- W2341004048 hasConcept C13965031 @default.
- W2341004048 hasConcept C161790260 @default.
- W2341004048 hasConcept C178790620 @default.
- W2341004048 hasConcept C179104552 @default.
- W2341004048 hasConcept C185592680 @default.
- W2341004048 hasConcept C191897082 @default.
- W2341004048 hasConcept C192562407 @default.
- W2341004048 hasConcept C199360897 @default.
- W2341004048 hasConcept C2777581544 @default.
- W2341004048 hasConcept C2779607525 @default.
- W2341004048 hasConcept C2779851234 @default.
- W2341004048 hasConcept C41008148 @default.
- W2341004048 hasConcept C64452783 @default.
- W2341004048 hasConceptScore W2341004048C113196181 @default.
- W2341004048 hasConceptScore W2341004048C134121241 @default.
- W2341004048 hasConceptScore W2341004048C13965031 @default.
- W2341004048 hasConceptScore W2341004048C161790260 @default.
- W2341004048 hasConceptScore W2341004048C178790620 @default.
- W2341004048 hasConceptScore W2341004048C179104552 @default.
- W2341004048 hasConceptScore W2341004048C185592680 @default.
- W2341004048 hasConceptScore W2341004048C191897082 @default.
- W2341004048 hasConceptScore W2341004048C192562407 @default.
- W2341004048 hasConceptScore W2341004048C199360897 @default.
- W2341004048 hasConceptScore W2341004048C2777581544 @default.
- W2341004048 hasConceptScore W2341004048C2779607525 @default.
- W2341004048 hasConceptScore W2341004048C2779851234 @default.
- W2341004048 hasConceptScore W2341004048C41008148 @default.
- W2341004048 hasConceptScore W2341004048C64452783 @default.
- W2341004048 hasLocation W23410040481 @default.
- W2341004048 hasOpenAccess W2341004048 @default.
- W2341004048 hasPrimaryLocation W23410040481 @default.
- W2341004048 hasRelatedWork W156414896 @default.
- W2341004048 hasRelatedWork W1986032923 @default.
- W2341004048 hasRelatedWork W2029062946 @default.
- W2341004048 hasRelatedWork W2048289715 @default.
- W2341004048 hasRelatedWork W2049598000 @default.
- W2341004048 hasRelatedWork W2082823086 @default.
- W2341004048 hasRelatedWork W2323474657 @default.
- W2341004048 hasRelatedWork W2371921317 @default.
- W2341004048 hasRelatedWork W2375305559 @default.
- W2341004048 hasRelatedWork W2391960384 @default.
- W2341004048 hasRelatedWork W2401354076 @default.
- W2341004048 hasRelatedWork W2794048740 @default.
- W2341004048 hasRelatedWork W2950435610 @default.
- W2341004048 hasRelatedWork W3047035419 @default.
- W2341004048 hasRelatedWork W3140586842 @default.
- W2341004048 hasRelatedWork W3150733556 @default.
- W2341004048 hasRelatedWork W3200142343 @default.
- W2341004048 hasRelatedWork W332176952 @default.
- W2341004048 hasRelatedWork W72509899 @default.
- W2341004048 hasRelatedWork W82755657 @default.
- W2341004048 isParatext "false" @default.
- W2341004048 isRetracted "false" @default.
- W2341004048 magId "2341004048" @default.
- W2341004048 workType "article" @default.