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- W2341350677 abstract "Ionic liquids with electron-donating anions are used to investigate rates and mechanisms of photoinduced bimolecular electron transfer to the photoexcited acceptor 9,10-dicyanoanthracene (9,10-DCNA). The set of five cyano anion ILs studied comprises the 1-ethyl-3-methylimidazolium cation paired with each of these five anions: selenocyanate, thiocyanate, dicyanamide, tricyanomethanide, and tetracyanoborate. Measurements with these anions dilute in acetonitrile and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide show that the selenocyanate and tricyanomethanide anions are strong quenchers of the 9,10-DCNA fluorescence, thiocyanate is a moderately strong quencher, dicyanamide is a weak quencher, and no quenching is observed for tetracyanoborate. Quenching rates are obtained from both time-resolved fluorescence transients and time-integrated spectra. Application of a Smoluchowski diffusion-and-reaction model showed that the complex kinetics observed can be fit using only two adjustable parameters, D and V0, where D is the relative diffusion coefficient between donor and acceptor and V0 is the value of the electronic coupling at donor-acceptor contact." @default.
- W2341350677 created "2016-06-24" @default.
- W2341350677 creator A5022538902 @default.
- W2341350677 creator A5032749422 @default.
- W2341350677 creator A5049003918 @default.
- W2341350677 creator A5072333217 @default.
- W2341350677 date "2015-11-09" @default.
- W2341350677 modified "2023-10-16" @default.
- W2341350677 title "Photoinduced Bimolecular Electron Transfer from Cyano Anions in Ionic Liquids" @default.
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- W2341350677 doi "https://doi.org/10.1021/acs.jpcb.5b09216" @default.
- W2341350677 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26501776" @default.
- W2341350677 hasPublicationYear "2015" @default.
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