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• W2341386101 abstract "New catalysts based on Yb(salen) complexes active for the copolymerization of cyclohexene oxide (CHO) and CO2 to give poly(cyclohexene)carbonate (PCHC) are reported. In combination with cocatalytic, nucleophilic chloride additives these new (binary) catalysts provided good conversion and selectivity for PCHC formation with average turnover frequencies of up to 35 h–1 and narrow molecular weight distributions. The best results were obtained with the binary catalyst system 1 (0.1 mol %)/NBu4Cl (0.05 mol %); at 90 °C a conversion of 57% was reached after 18 h with a TOF of 31 h–1, and the polycarbonate had an Mn of 10.2 kg/mol and a PDI of 1.54. Comparative catalysis studies have also been performed with a series of literature systems based on transition metal/lanthanide salen complexes, and the newly presented catalysts show comparatively good activity as well as copolymerization selectivity. MALDI-ToF mass spectrometric analysis revealed that trace water contamination and/or traces of 1,2-cyclohexanediol w..." @default.
• W2341386101 created "2016-06-24" @default.
• W2341386101 creator A5003571345 @default.
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• W2341386101 date "2015-11-11" @default.
• W2341386101 modified "2023-10-16" @default.
• W2341386101 title "Copolymerization of CO₂ and Cyclohexene Oxide Mediated by Yb(salen)-Based Complexes" @default.
• W2341386101 cites W1927730430 @default.
• W2341386101 cites W1963645635 @default.
• W2341386101 cites W1965213743 @default.
• W2341386101 cites W1972027918 @default.
• W2341386101 cites W1972842493 @default.
• W2341386101 cites W1980719770 @default.
• W2341386101 cites W1981512732 @default.
• W2341386101 cites W1982186111 @default.
• W2341386101 cites W1988212418 @default.
• W2341386101 cites W1988593925 @default.
• W2341386101 cites W1990727323 @default.
• W2341386101 cites W1991001415 @default.
• W2341386101 cites W1993403734 @default.
• W2341386101 cites W1996368029 @default.
• W2341386101 cites W1999514839 @default.
• W2341386101 cites W2000820554 @default.
• W2341386101 cites W2003135711 @default.
• W2341386101 cites W2007903961 @default.
• W2341386101 cites W2008643556 @default.
• W2341386101 cites W2011629150 @default.
• W2341386101 cites W2011887848 @default.
• W2341386101 cites W2017055412 @default.
• W2341386101 cites W2017928980 @default.
• W2341386101 cites W2019500081 @default.
• W2341386101 cites W2022101043 @default.
• W2341386101 cites W2024459961 @default.
• W2341386101 cites W2026285324 @default.
• W2341386101 cites W2026941394 @default.
• W2341386101 cites W2031182629 @default.
• W2341386101 cites W2031791596 @default.
• W2341386101 cites W2035559468 @default.
• W2341386101 cites W2041114591 @default.
• W2341386101 cites W2043063480 @default.
• W2341386101 cites W2044508107 @default.
• W2341386101 cites W2049203091 @default.
• W2341386101 cites W2058599232 @default.
• W2341386101 cites W2060406819 @default.
• W2341386101 cites W2064166918 @default.
• W2341386101 cites W2064216426 @default.
• W2341386101 cites W2068935670 @default.
• W2341386101 cites W2069684795 @default.
• W2341386101 cites W2070791658 @default.
• W2341386101 cites W2072332647 @default.
• W2341386101 cites W2080898720 @default.
• W2341386101 cites W2082554462 @default.
• W2341386101 cites W2085881347 @default.
• W2341386101 cites W2088791463 @default.
• W2341386101 cites W2094597708 @default.
• W2341386101 cites W2095710560 @default.
• W2341386101 cites W2098249838 @default.
• W2341386101 cites W2107983067 @default.
• W2341386101 cites W2113003934 @default.
• W2341386101 cites W2113703192 @default.
• W2341386101 cites W2122132793 @default.
• W2341386101 cites W2123502076 @default.
• W2341386101 cites W2132912197 @default.
• W2341386101 cites W2134593512 @default.
• W2341386101 cites W2141935251 @default.
• W2341386101 cites W2142476184 @default.
• W2341386101 cites W2144332006 @default.
• W2341386101 cites W2145023151 @default.
• W2341386101 cites W2149241459 @default.
• W2341386101 cites W2149749098 @default.
• W2341386101 cites W2151103222 @default.
• W2341386101 cites W2151296552 @default.
• W2341386101 cites W2153103446 @default.
• W2341386101 cites W2160489452 @default.
• W2341386101 cites W2161652710 @default.
• W2341386101 cites W2164621284 @default.
• W2341386101 cites W2317807208 @default.
• W2341386101 cites W2319195884 @default.
• W2341386101 cites W2322844794 @default.
• W2341386101 cites W2324471852 @default.
• W2341386101 cites W2330745941 @default.
• W2341386101 cites W2401540366 @default.
• W2341386101 cites W2507782625 @default.
• W2341386101 cites W2518020190 @default.
• W2341386101 cites W2951348789 @default.
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• W2341386101 doi "https://doi.org/10.1021/acs.macromol.5b01880" @default.
• W2341386101 hasPublicationYear "2015" @default.
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