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- W2341508907 abstract "The molar rotatory power in hydrocarbon solution of poly[(S)-1-methyl propyl]vinyl ether (I) is far higher than that of poly[(S)-2-methyl butyl]vinyl ether (II). With increasing temperature, the molar rotatory power of (I) decreases greatly, whereas that of (II) increases very slightly. The comparison of O.R.D. of (I) and (II) in the absence of complexing agents and in the presence of Al(i-C4H9)3 with that of low molecular weight model compounds has allowed some reasonable hypotheses to be drawn which explain, at least in part, the different behavior shown by the two polymers, and suggest that the relationships between optical activity and polymer structure are qualitatively the same in polyvinyl ethers and poly-α-olefins. The change of rotation of polyvinyl ethers by complexation with Al(iC4H9)3 is qualitatively consistent with the behavior of the low molecular weight models and, at least in the case of (II), dependent on polymer stereo-regularity." @default.
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- W2341508907 date "1967-01-01" @default.
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- W2341508907 title "Optically active vinyl polymers. XV. The optical activity in hydrocarbon solution of poly[(s)-1-methyl propyl]vinyl ether and of poly[(s)-2-methyl butyl] vinyl ether" @default.
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- W2341508907 doi "https://doi.org/10.1002/polc.5070160623" @default.
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