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• W2341727542 startingPage "367" @default.
• W2341727542 abstract "Diffusive gradients in thin films (DGT) devices were used to investigate the temporal and spatial changes in vanadium (V) speciation in the Churchill estuary system (Manitoba). Thirty-six DGT sets and 95 discrete water samples were collected at 8 river and 3 estuary sites during spring freshet and summer base flow. Dissolved V concentration in the Churchill River at summer base flow was approximately 5 times higher than those during the spring high flow (27.3 ± 18.9 nM vs 4.8 ± 3.5 nM). DGT-labile V showed an opposite trend with greater values found during the spring high flow (2.6 ± 1.8 nM vs 1.4 ± 0.3 nM). Parallel factor analysis (PARAFAC) conducted on 95 excitation-emission matrix spectra validated four humic-like (C1C4) and one protein-like (C5) fluorescent components. Significant positive relationship was found between protein-like DOM and DGT-labile V (r = 0.53, p < 0.05), indicating that protein-like DOM possibly affected the DGT-labile V concentration in Churchill River. Sediment leachates were enriched in DGT-labile V and protein-like DOM, which can be readily released when river sediment began to thaw during spring freshet." @default.
• W2341727542 created "2016-06-24" @default.
• W2341727542 creator A5017401964 @default.
• W2341727542 creator A5041749580 @default.
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• W2341727542 date "2016-07-01" @default.
• W2341727542 modified "2023-10-18" @default.
• W2341727542 title "Influence of dissolved organic matter on dissolved vanadium speciation in the Churchill River estuary (Manitoba, Canada)" @default.
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• W2341727542 doi "https://doi.org/10.1016/j.chemosphere.2016.03.124" @default.
• W2341727542 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27065459" @default.
• W2341727542 hasPublicationYear "2016" @default.
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