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- W2342506021 endingPage "9207" @default.
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- W2342506021 abstract "We have developed a highly selective method for the synthesis of α,β-unsaturated amides and alkenyl nitriles from readily available propargylic alcohols. The reaction proceeded smoothly under the neutral conditions with hydroxylamine hydrochloride (NH2OH·HCl) as the nitrogen source. The development of these new strategies has significantly extended the application of hydroxylamine hydrochloride to the chemistry of propargylic alcohols. Moreover, both secondary and tertiary alcohols have been highly regioselectively transformed to the desired products with good functional group compatibility." @default.
- W2342506021 created "2016-06-24" @default.
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- W2342506021 date "2015-09-01" @default.
- W2342506021 modified "2023-10-15" @default.
- W2342506021 title "Lewis Acid Mediated Tandem Reaction of Propargylic Alcohols with Hydroxylamine Hydrochloride To Give α,β-Unsaturated Amides and Alkenyl Nitriles" @default.
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- W2342506021 doi "https://doi.org/10.1021/acs.joc.5b01633" @default.
- W2342506021 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26317753" @default.
- W2342506021 hasPublicationYear "2015" @default.
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