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• W2343202860 endingPage "174" @default.
• W2343202860 startingPage "163" @default.
• W2343202860 abstract "The aim of this study was to design a hydrogel system based on methacrylated chondroitin sulfate (CSMA) and a thermo-sensitive poly(N-(2-hydroxypropyl) methacrylamide-mono/dilactate)-polyethylene glycol triblock copolymer (M15P10) as a suitable material for additive manufacturing of scaffolds. CSMA was synthesized by reaction of chondroitin sulfate with glycidyl methacrylate (GMA) in dimethylsulfoxide at 50 °C and its degree of methacrylation was tunable up to 48.5%, by changing reaction time and GMA feed. Unlike polymer solutions composed of CSMA alone (20% w/w), mixtures based on 2% w/w of CSMA and 18% of M15P10 showed strain-softening, thermo-sensitive and shear-thinning properties more pronounced than those found for polymer solutions based on M15P10 alone. Additionally, they displayed a yield stress of 19.2 ± 7.0 Pa. The 3D printing of this hydrogel resulted in the generation of constructs with tailorable porosity and good handling properties. Finally, embedded chondrogenic cells remained viable and proliferating over a culture period of 6 days. The hydrogel described herein represents a promising biomaterial for cartilage 3D printing applications." @default.
• W2343202860 created "2016-06-24" @default.
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• W2343202860 date "2016-09-01" @default.
• W2343202860 modified "2023-10-05" @default.
• W2343202860 title "A thermo-responsive and photo-polymerizable chondroitin sulfate-based hydrogel for 3D printing applications" @default.
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• W2343202860 doi "https://doi.org/10.1016/j.carbpol.2016.04.080" @default.
• W2343202860 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/27261741" @default.
• W2343202860 hasPublicationYear "2016" @default.
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