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- W2343291216 abstract "The organoplatinum(H) compounds [(2,6-(MezNCH,J2C6H,)PtBr] and cis-[(C-N)2Pt] (C-N = 2-Me2 NCH, C’, H4, 2-MezNC6 H4 CH,) can be chemically irreversibly oxidized in the potential range 1.00 to 1.3.5 V vs. an Ag/AgCI electrode, whereas the organoplatinum-mercury complexes [(2,6-(MezNCHz )z C, H&R CO2 )PtHg( 0, CR)Br] and [(C-NJ? (p-l-0,0’-RCOz)PtHg(OzCR)] (R = Me) could only be reduced, in the potential range -0.20 to -0.70 V, resulting in deposition of metallic mercury on the electrode. Reoxidation of the mercury occurred in the potential range +l.OO to +I.20 V. Both the organoplatinum(II) and organoplatinum-mercury complexes (R = i-Pr) showed strong U. V. absolptions below 320 nm, which are assigned to Metal-to-Ligand Charge Transfer transitions. i%e bis-benzyl platinum-mercury compound ((2Me2NC6H4CH2)2(p-0,0’-i-PrCOz)PtHg(02C-i-Pr)] showed an additional strong absorption, assigned to a u-o* transition, at 335 nm. The results have been interpreted as indicating the presence for the Pt-Hg complexes of a metal-metal bond, either covalent or donative, involving interaction of an initially filled, high energy orbital on Pt and an empty orbital on Hg." @default.
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- W2343291216 date "1982-01-01" @default.
- W2343291216 modified "2023-09-22" @default.
- W2343291216 title "Electronic and Electrochemical Properties of Platinum(H) and Platinum- mercury-carboxylato Complexes Containing 2-Me2NCH&H4-, 2,6-(Me,NCH,),- C,H,- and 2-Me2NC,H,CH, Ligands" @default.
- W2343291216 hasPublicationYear "1982" @default.
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