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- W2343564673 abstract "Three BINOL-derived phosphoric acids exhibiting atropisomerism in the 3,3′-positions were obtained by Suzuki coupling reaction. The diastereomeric mixture was resolved by HPLC. Structural assignment was achieved by NOE-NMR analysis and by TD-DFT simulation of the electronic circular dichroism (ECD) spectra. The three atropisomeric catalysts were tested in three enantioselective reactions, comparing their ability to induce enantioselectivity with related, well-known, phosphoric acid structures. All three catalysts were competent in promoting the reactions, rendering excellent enantioselectivity (98 % ee) in one case. The atropisomeric features at the 3,3′-position were indeed found to influence the outcome of the reaction, demonstrating the potential of atropisomeric conformational control at the 3,3′-position of the BINOL core in the rationalization of catalyst performances and in the design of new efficient structures." @default.
- W2343564673 created "2016-06-24" @default.
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- W2343564673 date "2016-05-02" @default.
- W2343564673 modified "2023-09-27" @default.
- W2343564673 title "An Atropisomerically Enforced Phosphoric Acid for Organocatalytic Asymmetric Reactions" @default.
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- W2343564673 doi "https://doi.org/10.1002/ejoc.201600296" @default.
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