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- W2344118001 endingPage "763" @default.
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- W2344118001 abstract "The enantiopure salt Δ-[Co((S,S)-dpen)3]3+2Cl–B(C6F5)4– is an effective hydrogen bond donor catalyst for additions of 1,3-dicarbonyl compounds to di-tert-butyl azodicarboxylate in the presence of N-methylmorpholine (1.0:1.0:0.10) in CH3CN at 0 °C, as illustrated with educts derived from five- or six-membered ring ketones (99–88% yields, >99–91% ee) and cycloheptanone (94%, 72% ee) as well as 2-cyanocyclopentanone (92%, 45% ee) and an acyclic system (98%, >99% ee)." @default.
- W2344118001 created "2016-06-24" @default.
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- W2344118001 date "2016-01-28" @default.
- W2344118001 modified "2023-10-10" @default.
- W2344118001 title "Tris(1,2-diphenylethylenediamine)cobalt(III) Complexes: Chiral Hydrogen Bond Donor Catalysts for Enantioselective α-Aminations of 1,3-Dicarbonyl Compounds" @default.
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- W2344118001 doi "https://doi.org/10.1021/acs.orglett.6b00023" @default.
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