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- W2344133333 abstract "The effects of plasticization and cross-linking on the performance of chitosan as promising proton exchange membranes (PEMs) for bioelectricity generation in microbial fuel cells (MFCs) were investigated. The physico-chemical properties of chitosan (CS), sorbitol-chitosan (S-CS), phosphorylated-chitosan (CS-P) and phosphorylated-sorbitol-chitosan (S-CS-P) membranes were investigated by FESEM-EDS, FTIR-ATR, XRD, TGA, tensile strength and sorption studies. The performance of the fabricated PEMs was assessed by power density and cation exchange capacity (CEC). Maximum power densities achieved were 130.03, 20.76, 94.59 and 7.42mW/m(2) for CS-P, S-CS-P, S-CS and CS membranes respectively. Phosphorylation of the CS membranes increased CEC and tensile strength, attributed to an increase in bonded amide and phosphate ionic surface groups. Further, 49.07% COD removal from municipal wastewater was achieved with CS-P membranes. Thus, through chemical modifications, the physico-chemical and mechanical properties of natural abundant biopolymer chitosan can be enhanced for its use as an environmentally sustainable PEM in MFC technology." @default.
- W2344133333 created "2016-06-24" @default.
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- W2344133333 creator A5058467478 @default.
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- W2344133333 date "2016-09-01" @default.
- W2344133333 modified "2023-09-26" @default.
- W2344133333 title "Enhanced surface functionality and microbial fuel cell performance of chitosan membranes through phosphorylation" @default.
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- W2344133333 doi "https://doi.org/10.1016/j.carbpol.2016.04.118" @default.
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