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• W2344581246 abstract "Catalytic conditions for the α-arylation of aryl nitromethanes have been discovered using parallel microscale experimentation, despite two prior reports of the lack of reactivity of these aryl nitromethane precursors. The method efficiently provides a variety of substituted, isolable diaryl nitromethanes. In addition, it is possible to sequentially append two different aryl groups to nitromethane. Mild oxidation conditions were identified to afford the corresponding benzophenones via the Nef reaction, and reduction conditions were optimized to afford several diaryl methylamines." @default.
• W2344581246 created "2016-06-24" @default.
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• W2344581246 date "2015-11-20" @default.
• W2344581246 modified "2023-10-17" @default.
• W2344581246 title "Palladium-Catalyzed α-Arylation of Aryl Nitromethanes" @default.
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• W2344581246 doi "https://doi.org/10.1021/acs.orglett.5b02793" @default.
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