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- W2344615690 abstract "A significant enhancement of the yttrium-stabilized zirconia-supported palladium (0.2 wt % Pd/YSZ) catalytic activity for the total oxidation of methane was achieved in a dual-bed system by the association of LaMnO3+Pd/YSZ materials. The combination with the best performance was 40 wt % LaMnO3+60 wt % Pd/YSZ. Pd/YSZ and LaMnO3 perovskite were characterized by using the 18O2 exchange technique. A Mars–van Krevelen mechanism was demonstrated over Pd/YSZ at 425 °C. Additionally, it was evidenced that LaMnO3 activated the O2 molecule on the YSZ oxygen vacancy sites to result in a significant increase of the oxidation rate characterized by a correlating decrease of the light-off temperature of 65 °C." @default.
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- W2344615690 date "2016-05-30" @default.
- W2344615690 modified "2023-09-25" @default.
- W2344615690 title "Study of Lanthanum Manganate and Yttrium-Stabilized Zirconia-Supported Palladium Dual-Bed Catalyst System for the Total Oxidation of Methane: A Study by 18 O2 /16 O2 Isotopic Exchange" @default.
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- W2344615690 doi "https://doi.org/10.1002/cctc.201600598" @default.
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