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- W2344714481 abstract "Two novel polyoxometalate (POM)-based organic–inorganic hybrids, namely, [(CH3)2NH2][Co(tpba)(Mo2O7)]·2H2O (1) and [(CH3)2NH2][Ni(tpba)(Mo2O7)]·2H2O (2) (tpba = 4-([4,2′:6′,4′′-terpyridin]-4′-yl)benzoic acid), have been synthesized and characterized by elemental analyses, IR spectra, TG analyses and single-crystal X-ray diffraction. Compounds 1 and 2 are isostructural and feature microporous interpenetrated frameworks, which are constructed from metal–organic layers pillared by the [Mo2O7]2 − anions. Topologically, the overall structures of 1 and 2 can be classified as a rare (3,5)-connected twofold interpenetrated hms net, which has never been observed in POM-based hybrid materials prior to this work. Furthermore, the magnetic property of compound 1 are discussed." @default.
- W2344714481 created "2016-06-24" @default.
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- W2344714481 date "2016-07-01" @default.
- W2344714481 modified "2023-10-18" @default.
- W2344714481 title "Two novel molybdenum-oxide-based organic-inorganic hybrid frameworks exhibiting twofold interpenetrated hms networks" @default.
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- W2344714481 doi "https://doi.org/10.1016/j.inoche.2016.04.028" @default.
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