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- W2345107029 abstract "Abstract Three amino-functionalized coordination polymers with different flexible V-shaped dicarboxylate ligands have been synthesized based on Cd salt and a rigid linear ligand L (L = 3,6-di(3-imidazolyl)benzene-1,2-diamine, H2HIP = 5-hydroxyisophthalic acid, H2ABA = bis(4-carboxylphenyl)amine, H2IBG = isophthaloylbisglycine): {[Cd(L)1.5(HIP)]·(H2O)}n (1), {[Cd2(L)(ABA)2(H2O)]·(H2O)2}n (2) and {[Cd(L)0.5(IBG)]·(H2O)2}n (3). Complex 1 crystallizes in a mononuclear structure with a 3D hxg-d net. Complex 2 crystallizes in a tetranuclear fashion with a layer structure. Complex 3 shows an infinite rod-shaped secondary building unit (SBU) structure. It implies that the structural diversity in assembly process is determined by the flexibility of dicarboxylate ligands. These complexes were characterized by single crystal X-ray diffraction, infrared spectra, thermogravimetric analysis, elemental analysis, and powder X-ray diffraction measurements. Additionally, luminescent properties of 1–3 have also been explored and all exhibit significant red-shifted emission in the solid state at room temperature compared with free L ligand." @default.
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- W2345107029 date "2016-07-01" @default.
- W2345107029 modified "2023-10-14" @default.
- W2345107029 title "Dicarboxylate-dependent structural diversity in amino-functionalized complexes: From mononuclear to multinuclear coordination polymer" @default.
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- W2345107029 doi "https://doi.org/10.1016/j.inoche.2016.04.016" @default.
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