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- W2345472145 endingPage "8083" @default.
- W2345472145 startingPage "8078" @default.
- W2345472145 abstract "Asymmetric synthesis of tetrahydrobenzodiazepines was achieved by transfer hydrogenation of dihydrobenzodiazepines with benzothiazoline having a hydrogen-bonding donor substituent by means of a newly synthesized chiral phosphoric acid. This method was applicable to various racemic dihydrobenzodiazepines to give the corresponding products in good yields with excellent diastereoselectivities and enantioselectivities taking advantage of the dynamic kinetic resolution. Furthermore, the effect of bulky substituent at 3,3'-position on the catalyst and hydrogen-bonding donor substituent on benzothiazoline was fully elucidated by the theoretical study." @default.
- W2345472145 created "2016-06-24" @default.
- W2345472145 creator A5025592777 @default.
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- W2345472145 creator A5047852267 @default.
- W2345472145 creator A5075446830 @default.
- W2345472145 creator A5082575641 @default.
- W2345472145 date "2016-05-06" @default.
- W2345472145 modified "2023-10-18" @default.
- W2345472145 title "Dynamic Kinetic Resolution Approach for the Asymmetric Synthesis of Tetrahydrobenzodiazepines Using Transfer Hydrogenation by Chiral Phosphoric Acid" @default.
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