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• W2345722732 endingPage "8151" @default.
• W2345722732 startingPage "8137" @default.
• W2345722732 abstract "The difluoromethylene (CF2 ) group has a strong tendency to adopt corner over edge locations in aliphatic macrocycles. In this study, the CF2 group has been introduced into musk relevant macrocyclic ketones. Nine civetone and five muscone analogues have been prepared by synthesis for structure and odour comparisons. X-ray studies indeed show that the CF2 groups influence ring structure and they give some insight into the preferred ring conformations, triggering a musk odour as determined in a professional perfumery environment. The historical conformational model of Bersuker and co-workers for musk fragrance generally holds, and structures that become distorted from this consensus, by the particular placement of the CF2 groups, lose their musk fragrance and become less pleasant." @default.
• W2345722732 created "2016-06-24" @default.
• W2345722732 creator A5018458100 @default.
• W2345722732 creator A5023041075 @default.
• W2345722732 creator A5027145763 @default.
• W2345722732 creator A5045022989 @default.
• W2345722732 creator A5049970193 @default.
• W2345722732 creator A5082091702 @default.
• W2345722732 creator A5004973150 @default.
• W2345722732 date "2016-05-06" @default.
• W2345722732 modified "2023-10-16" @default.
• W2345722732 title "Fluorinated Musk Fragrances: The CF₂Group as a Conformational Bias Influencing the Odour of Civetone and (<i>R</i>)-Muscone" @default.
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