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• W2345773075 endingPage "3080" @default.
• W2345773075 startingPage "3076" @default.
• W2345773075 abstract "Water molecule-driven reversible phase transitions up to 450 °C have been observed for the first time in a novel selenite crystal, LiSc(SeO3)2·H2O, through single-crystal-to-single-crystal (SCSC) transformations. Single crystal X-ray diffraction suggests that LiSc(SeO3)2·H2O (P2/c) transforms to LiSc(SeO3)2·0.5H2O (P1̅), LiSc(SeO3)2·0.25H2O (P1̅), and α-LiSc(SeO3)2 (I–42d) at 170–190, 200–230, and 240–450 °C, respectively. The structural evolution is attributable to the different positions of Li+ cations within the eight-membered ring (8-MR) channel, in which the amount of water molecules plays a key role in determining the coordination environment and the subsequent location of Li+ cations. Further heating of the crystal to 500 °C results in a remarkably stable β-LiSc(SeO3)2 (R3̅)." @default.
• W2345773075 created "2016-06-24" @default.
• W2345773075 creator A5054799694 @default.
• W2345773075 creator A5072456477 @default.
• W2345773075 date "2016-05-05" @default.
• W2345773075 modified "2023-10-16" @default.
• W2345773075 title "LiSc(SeO₃)₂·<i>x</i>H₂O (0 ≤ <i>x</i> ≤ 1): New Selenites Revealing Water Molecule-Driven Extremely High Temperature Single-Crystal-to-Single-Crystal Transformations" @default.
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• W2345773075 doi "https://doi.org/10.1021/acs.cgd.6b00519" @default.
• W2345773075 hasPublicationYear "2016" @default.
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