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- W2345806094 startingPage "2159" @default.
- W2345806094 abstract "合成了4－氰基苯基咪唑并[5,6-f]邻菲咯啉（CYIP）和2－羧基苯基咪唑并[5,6-f]邻菲咯啉（COIP）两种新配体及它们的钌混配配合物[Ru(bpy)2CYIP](ClO4)2·H2O（Rul）（bpy=2,2′-联吡啶），[Ru(phen)2CYIP](ClO4)2·H2O(Ru2)(phen=1,10-邻菲咯啉），[Ru(bpy)2COIP](ClO4)2·3H2O(Ru3)和[Ru(phen)2COIP](ClO4)2·H2O(Ru4)，并用红外光谱、紫外光谱、核磁和质谱对它们进行了表征。通过循环伏安法研究了这些配合物的电化学性质。采用电子吸收光谱、稳态荧光、圆二色谱和粘度测定研究了配合物与小牛胸腺DNA的相互作用。结果表明配合物Rul和Ru2通过CYIP配体以插入的方式与DNA结合，而配合物Ru3和Ru4则通过COIP配体以部分插入的方式与DNA结合。" @default.
- W2345806094 created "2016-06-24" @default.
- W2345806094 creator A5013186419 @default.
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- W2345806094 date "2002-12-15" @default.
- W2345806094 modified "2023-09-23" @default.
- W2345806094 title "配体的空间构型及疏水性对钌（II）多吡啶配合物与DNA作用的影响" @default.
- W2345806094 hasPublicationYear "2002" @default.
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