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- W2346280109 abstract "在含三乙醇胺、酒石酸钠的氢氧化钠溶液(pH 12.5)中,镁(Ⅱ)与铬蓝黑R(简钧EBBR)在-0.98V(对SCE)处有一灵敏、对称的示波极谱电流,镁(Ⅱ)浓度在1.7×10~(-7)～2.5×10~(-5)mol/L和峰高成正比,检出限5.5×10~(-8)mol/LMg(Ⅱ)。配合物至少稳定12小时。方法可用于纯镍和镍基高温合金中微量镁的测定。文中研究了其配合比、电流特性及电极反应的可逆性,计算了其条件稳定常数(β)、电子转移数(n)及其系数(α),还讨论试剂结构对其镁(Ⅱ)配合物电活性的影响。" @default.
- W2346280109 created "2016-06-24" @default.
- W2346280109 creator A5027201786 @default.
- W2346280109 creator A5060657941 @default.
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- W2346280109 date "1990-02-28" @default.
- W2346280109 modified "2023-09-24" @default.
- W2346280109 title "镁(II)—铬蓝黑R配合物电化学行为的研究和分析应用" @default.
- W2346280109 hasPublicationYear "1990" @default.
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