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- W2346344051 abstract "本文合成了1对手性双核钌（Ⅱ）配合物△△-和从。【（bpy）2Ru（mbp-hH2）Ru（bpy）2]（C104）4（bpy=2，2’-联吡啶，mbpibH2=1，3-二（咪唑并【4，5-fⅡ1，10-邻菲咯啉】）苯）。通过元素分析、质谱、核磁共振、CD光谱对这两个化合物进行了结构表征。采用循环伏安法对配合物的电化学性质进行了分析。利用紫外一可见吸收光谱滴定、荧光光谱滴定、稳态荧光淬灭和粘度实验研究了配合物与DNA的相互作用。实验结果表明这2个配合物都能以插入的方式与DNA键合，而且△△配合物的DNA结合强度稍强于从配合物。" @default.
- W2346344051 created "2016-06-24" @default.
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- W2346344051 date "2008-01-01" @default.
- W2346344051 modified "2023-09-24" @default.
- W2346344051 title "手性双核钌（II）配合物与DNA的相互作用研究" @default.
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