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- W2346393611 abstract "We report here the synthesis and study of a multipodal ligand bearing three CMPO units attached to a trialkylphosphine oxide cap along with the resultant Ln3+, Th4+ and UO22+ metal complexes. This tripodal ligand demonstrates extraction efficiencies of 47% and 44% for the actinide species Th(NO3)4 and UO2(NO3)2 out of 1 M nitric acid into a solution of dichloromethane, while all lanthanide nitrates were extracted with relatively low efficiencies. Further extraction studies utilizing 5 M nitric acid solutions resulted in nearly quantitative actinide extraction. The ability of this ligand to sensitize the metal-centered luminescence of Eu3+ and Tb3+ in DMSO solutions was also investigated. Finally, possible conformations for the structure of the [La(NO3)-ligand]2+ complex were calculated using density functional theory." @default.
- W2346393611 created "2016-06-24" @default.
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- W2346393611 date "2016-08-01" @default.
- W2346393611 modified "2023-09-25" @default.
- W2346393611 title "f-Element coordination and extraction selectivity of a carbamoylmethylphosphine oxide ligand based on a tripodal phosphine oxide scaffold" @default.
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- W2346393611 doi "https://doi.org/10.1016/j.ica.2016.05.003" @default.
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