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- W2346543263 abstract "The title compound, [Cu2I2(CH3CN)4], exhibits a centrosymmetric Cu2I2 core [Cu⋯Cu distance = 2.7482 (11) Å], the Cu(I) atoms of which are further coordinated by four mol-ecules of aceto-nitrile. The Cu(I) atom has an overall distorted tetra-hedral coordination environment evidenced by L-Cu-L angles (L = N or I) ranging from 100.47 (10) to 117.06 (2)°. The coordination geometries of the aceto-nitrile ligands deviate slightly from linearity as shown by Cu-N-C angles of 167.0 (2) and 172.7 (2)°. In the crystal, there are no significant hydrogen-bonding inter-actions present, so the crystal packing seems to be formed predominantly by van der Waals forces." @default.
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- W2346543263 date "2015-10-03" @default.
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- W2346543263 title "Crystal structure of di-μ-iodido-bis[bis(acetonitrile-κ<i>N</i>)copper(I)]" @default.
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- W2346543263 doi "https://doi.org/10.1107/s2056989015018149" @default.
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