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- W2346574589 abstract "Abstract The effects Fe 2 O 3 nanoparticles on the thermal decomposition of nitrocellulose (NC) have been investigated by the differential scanning calorimetry (DSC) method and the thermogravimetry with Fourier transform infrared analysis (TG-IR). DSC analysis shows that Fe 2 O 3 can be safely used with NC, and the thermal decomposition reactions of Fe 2 O 3 -NC composite and NC follow the same thermal decomposition mechanism of Avrami-Erofeev equation f(α) = 1.5(1–α)[–ln(1–α)] 1/3 in differential form. The as-prepared nanoparticles could reduce the activation energy of the decomposition reaction and the critical temperature of thermal explosion of NC. In addition, TG-IR analysis indicated that Fe 2 O 3 nanoparticles play a crucial role in promoting the O NO 2 bond cleavage and secondary autocatalytic reactions in condensed phase. This contribution suggests that introducing Fe 2 O 3 nanostructure may be a promising way to accelerate the thermal decomposition of NC." @default.
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- W2346574589 date "2016-07-01" @default.
- W2346574589 modified "2023-10-16" @default.
- W2346574589 title "Effects of α-Fe2O3 nanoparticles on the thermal behavior and non-isothermal decomposition kinetics of nitrocellulose" @default.
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- W2346574589 doi "https://doi.org/10.1016/j.jaap.2016.05.002" @default.
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