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- W2346857628 abstract "Abstract Glass samples with composition xSrO-10PbO-(90-x)B 2 O 3 (x = 20, 25, 30, 35, 40 and 45) were prepared by melt-quenching method to elucidate the elastic behaviour due to borate anomaly. Structural investigation of glass samples were carried out by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy while elastic properties were studied by measuring both longitudinal and shear velocities using pulse-echo method at 5 MHz frequency. FTIR analysis revealed the presence of BO 4 and BO 3 vibration groups. Addition of SrO has resulted in increased ultrasonic velocities, elastic moduli ( C L , μ , K and Y ), hardness ( H ), Debye temperature ( θ D ) for SrO content up to 30% but decreased for higher SrO addition. The fraction of the four coordinated boron atoms (N 4 ) values, calculated from FTIR spectra increased for x ≤ 30 mol% followed by decrease at x > 30 mol%. Quantitative analysis of ultrasonic data using the bulk compression and ring deformation models showed reduction in the ratio of calculated bulk modulus to the experimental bulk modulus, K bc / K e for x ≤ 30 mol% indicating decreased ring deformation in borate anomaly region." @default.
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- W2346857628 date "2016-07-01" @default.
- W2346857628 modified "2023-09-23" @default.
- W2346857628 title "Anomalous elastic behaviour of xSrO-10PbO-(90-x)B2O3 glass system" @default.
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- W2346857628 doi "https://doi.org/10.1016/j.jnoncrysol.2016.04.038" @default.
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