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- W2347031151 abstract "Two novel ferrocene derivatives, N,N-diphenyl-4-E-((1-ferrocenyl) ethenyl) aniline (1), N,N-(4,4-diethoxyphenyl)-4-E-((1-ferrocenyl)ethenyl)aniline (2), were designed, synthesized and fully characterized by 1H NMR, 13C NMR, FT-IR and MALDI-TOF-MS spectra. Structure of (1) was confirmed by X-ray diffraction analysis. The UV–visible absorption spectra of the two compounds were investigated and verified by density functional theory (DFT) calculations. Electrochemical and third-order nonlinear optical (NLO) properties have been shown by cyclic voltammetric experiments and open/closed aperture Z-scan measurements. The results show that the two compounds both are highly π-electron delocalization system, indicating potential applications as NLO materials. It is noteworthy that (1) possesses larger two-photon absorption (2 PA) coefficient β, 2 PA cross section σ and the third-order nonlinear susceptibility (χ(3)) than (2)." @default.
- W2347031151 created "2016-06-24" @default.
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- W2347031151 date "2016-08-01" @default.
- W2347031151 modified "2023-10-18" @default.
- W2347031151 title "Synthesis, crystal structure, electrochemistry and third-order nonlinear optical properties of two novel ferrocene derivatives" @default.
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- W2347031151 doi "https://doi.org/10.1016/j.jorganchem.2016.04.032" @default.
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