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- W2347580049 abstract "By adding BF3·OEt2 (B) and its derivatives to the MoCl3 (C7H15 COO)2-(i-Bu )2 AlO- (Mo-Al) two-component catalyst system of synthesizing 1,2-polybutadi-ene with hydrogasoline as solvent, the catalytic activity was influenced remarkably. By addingthe product of HO -/BF3·OEt2 = 1. 0 to the catalyst system, the highest catalyt-ic activity of molybdenum carboxylate system was obtained for the first time. A conversion of more than 70% butadiene (Bd) was achieved with Mo/Bd = 8. 0×10-5(molar ratio) at 50℃ for 5hr. The conditions to produce the gel were preliminarily thrashed out in synthesizing 1, 2-polybutadiene with molybdenum catalyst system, and the reasons of producing the gel was inferred. The influence of the polymerization conditions on catalytic activity, molecular weight and microstructure was also investigated." @default.
- W2347580049 created "2016-06-24" @default.
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- W2347580049 date "1993-01-01" @default.
- W2347580049 modified "2023-09-23" @default.
- W2347580049 title "THE EFFECT OF BF_3·OEt_2 ON SYNTHESIZING 1,2-POLYBUTADIENE WITH MOLYBDENUM CATALYST SYSTEM" @default.
- W2347580049 hasPublicationYear "1993" @default.
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