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- W2347719963 abstract "To model active site structure of carbonic anhydrase (CA), we synthesized a series ofmetal complexes supported by tris(substituted pyrazolyl) hydroborato ligands TpR,R1MX (R = Ph, 2' - thie, Me; R1 = Ph, 2' - thie, Me; M = Co, Ni, Cu, Zn, Cd; X = Cl, NO3, CH3COO). These complexes were all characterized by elemental analysis, IR, and 1H NMR spectroscopy. Activity of five representatives selected from these complexes in catalyzing reversible hydration reaction of CO2 were investigated by the stopped - flow technique. It was showed that the reaction had general dynamic characteristics of enzyme - catalyzed reaction. The activity varied with the pH of reaction system, the structure (especially electric structure of metal ion) and concentration of the model complexes, along with some other important results were obtained. The activation energy of dehydration reaction in the presence and absence of model complexes were calculated, which may interpret well that the higher reaction rate essentially resulted from the decrease in activation energy of the reaction." @default.
- W2347719963 created "2016-06-24" @default.
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- W2347719963 date "1999-01-01" @default.
- W2347719963 modified "2023-09-23" @default.
- W2347719963 title "Investigation on Synthesis,Characterization and Catalytic Activity of Model Complexes of Carbonic Anhydrase" @default.
- W2347719963 hasPublicationYear "1999" @default.
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