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- W2347970147 abstract "Effect of ZrOCl2·8H2O doping on proton conductive properties of phosphosilicate gel was investigated by means of sol-gel method.The results prove that ZrOCl2·8H2O can increase proton conductivity of the gel,and that the sample with ZrOCl2·8H2O content of 0.97%(mass fraction) shows maximum proton conductivity of 2.38 S/m at 130 ℃.The doped samples,on which no H3PO4 were found to precipitate during storage under a condition of R.H.(relative humidity) 40% for a month,exhibited no apparent changes in proton conductive performances.NMR measurements revealed that introduction of ZrOCl2 to the gel could decrease the formation of isolated PO3-4 structural units and increase cross-linking between and tetrahedrons,thus resulted in an increase in both proton conductivity and chemical stability." @default.
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- W2347970147 date "2012-01-01" @default.
- W2347970147 modified "2023-09-25" @default.
- W2347970147 title "Effect of ZrOCl_2 Doping on Proton Conductive Performances of the Phosphosilicate Gels" @default.
- W2347970147 hasPublicationYear "2012" @default.
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