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- W2348398426 abstract "Three binuclear Ln(Ⅲ) coordination complexes,[Sm2(p-ClC6H4COO)6(phen)2(H2O)2](1),[Eu2(p-ClC6H4COO)6(phen)2(H2O)2](2),[Tb2(p-ClC6H4COO)6(phen)2](3),were hydrothermally synthesized and structurally characterized.The structural analysis shows that these three complexes have the same character.The central Ln(Ⅲ) ions are eight-coordinate,four p-chlorobenzoic acid ligands bridged two Ln(Ⅲ) ions,and the other two p-chlorobenzoic acid as terminal ligands.The IR,UV-Vis-NIR absorption spectra and the fluorescence spectra of complexes were measured at room temperature.In the visible region,these three complexes show the intense characteristic emissions band of the Ln(Ⅲ) ions.The emission of ligands is reduced greatly,even to be quenched.It indicates that the energy transfer from the ligand to the central Ln(Ⅲ) ion is efficient,i.e.,the ligand sensitizes luminescence of Ln(Ⅲ) ion.By comparison,the sensitization of ligand to the Ln(Ⅲ) ion in complexes(2) and(3) is more efficient than that in complex(1).It may be related to the characteristic of the intrinsic energy level of the Ln(Ⅲ) ion." @default.
- W2348398426 created "2016-06-24" @default.
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- W2348398426 date "2010-01-01" @default.
- W2348398426 modified "2023-09-28" @default.
- W2348398426 title "Synthesis,structure and photophysical property of a series of binuclear Ln(III) complexes" @default.
- W2348398426 hasPublicationYear "2010" @default.
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