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- W2348468777 abstract "Two isostructural heteronuclear complexes [Fe(phen)3]2[FeLn(H2O)(tiron)3].6H2O(Ln =Ho(1) and Yb(2)),Na2H2tiron=disodium 4,5-dihydro-xybenzene-1,3-disulfonate) were self-assembly synthesized via hydrothermal reaction.The complexes crystallized in the cubic system,space group P213.In [FeLn(H2O)(tiron)3]6-unit was revealed that the Fe3 + ion is in a FeO6 distorted trigonal anti-prism coordination polyhedron completed by six phenolate O atoms from three tiron4-ligands,and Ln3 + in a LnO7 distorted monocapped trigonal anti-prism coordination polyhedron completed by three phenolate μ2-O atoms and three O atoms from sulfonate groups of three ligands and one O atom from coordinated water.The [Fe(phen)3]3+ cations and [FeCe(tiron)3]6-anions via π-π interaction between phen ligands and electric attraction between cations and anions was assembled into multidimensional supramolecule.The magnetic properties of the complexes were been determined in the temperature range 2～300 K,indicating that the antiferromagnetic interaction between the central Ln(Ⅲ)-Fe(Ⅲ) ions.CCDC: 866880,1;867589,2." @default.
- W2348468777 created "2016-06-24" @default.
- W2348468777 creator A5007329624 @default.
- W2348468777 date "2013-01-01" @default.
- W2348468777 modified "2023-09-25" @default.
- W2348468777 title "Syntheses, Crystal Structures and Magnetic Properties of Two 3d-4f Heterometallic Complexes [Fe(phen)_3]_2[FeLn(H_2O)(tiron)_3]·6H_2O (Ln=Ho~III, Yb~III)" @default.
- W2348468777 hasPublicationYear "2013" @default.
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